Lei-Lei Jiaa,Li-Guo Zhonga(
Abstract
During heavy oil recovery in the Bohai Oilfield, substantial emulsification of oil and water occurred, primarily forming water-in-oil emulsions. This phenomenon could alter fluid dynamics within the subsurface porous media, potentially impacting well production performance. To elucidate the properties of water-in-oil emulsions and their associated liquid resistance effects, this study conducted a series of rheological tests, microscopic examinations, and injection experiments. The results show that the droplet size and distribution of water-in-oil emulsions were primarily influenced by shear rate and water content, which in turn modified emulsion viscosity. The stability of water-in-oil emulsions was reduced when they flowed through porous media. The increase in emulsion viscosity and the liquid resistance effect collectively enhanced the seepage resistance of water-in-oil emulsions flowing through porous media. Notably, when the emulsion droplet size exceeded the pore throat size, over 90% of the total seepage resistance was attributable to the liquid resistance effect. Conversely, when the majority of the emulsion droplets were smaller than the pore throat, the viscosity accounted for more than 60% of the seepage resistance. water-in-oil emulsions flowed through cores with permeabilities ranging from 50 to 100 mD, exhibiting threshold pressure gradients between 35 and 43 MPa/m. At a core permeability of 300 mD, the threshold pressure gradient was significantly reduced to 1 MPa/m. The presence of a water-in-oil emulsion in the reservoir could result in a production pressure differential falling below the threshold pressure, thereby reducing reservoir productivity.
References
Abdullah, M.M.S., Al-Lohedan, H.A., 2022. Alginate-based poly ionic liquids for the efficient demulsification of water in heavy crude oil emulsions. Fuel 320, 123949. https://doi.org/10.1016/j.fuel.2022.123949.
Adil, M., Onaizi, S.A., 2022. Pickering nanoemulsions and their mechanisms in enhancing oil recovery: a comprehensive review. Fuel 319, 123667. https://doi.org/10.1016/j.fuel.2022.123667.
Cao, C.X., Gu, S.H., Song, Z.J., Xie, Z.H., Chang, X.Y., Shen, P.P., 2022. The viscosifying behavior of W/O emulsion and its underlying mechanisms: considering the interfacial adsorption of heavy components. Colloid. Surface. 632, 127794. https://doi.org/10.1016/j.colsurfa.2021.127794.
Chen, C., Jing, Z.F., Feng, C., Feng, C., Zou, X., Qiao, M., Xu, D., Wang, S., 2023. Two-phase flow and morphology of the gas–liquid interface for bubbles or droplets in different microchannels. Phys. Fluids 35, 091302. https://doi.org/10.1063/5.0157473.
Ding, B.X., Dong, M.Z., Chen, Z.G., Kantzas, A., 2022. Enhanced oil recovery by emulsion injection in heterogeneous heavy oil reservoirs: experiments, modeling and reservoir simulation. J. Pet. Sci. Eng. 209, 109882. https://doi.org/10.1016/j.petrol.2021.109882.
Dong, B., Qin, Z.Y., Wang, Y.W., Zhang, J.H., Xu, Z., Liu, A.X., Guo, X.Q., 2022. Investigating the rheology and stability of heavy crude oil-in-water emulsions using APG08 emulsifiers. ACS Omega 7, 37736-37747. https://doi.org/10.1021/acsomega.2c04684.
Fani, M., Pourafshary, P., Mostaghimi, P., Mosavat, N., 2022. Application of microfluidics in chemical enhanced oil recovery: a review. Fuel 315, 123225. https://doi.org/10.1016/j.fuel.2022.123225.
Foxenberg, W.E., Ali, S.A., Ke, M., 1996. Effects of completion fluid loss on well productivity. In: SPE Formation Damage Control Symposium. https://doi.org/10.2118/31137-MS.
Gong, J.C., Ji, Y.F., Wang, Y.L., Fan, H.M., Wei, Z.Y., Li, C.Y., 2022. Preparation and interfacial behavior of surface-active microspheres for both emulsion stabilization and profile control. J. Pet. Sci. Eng. 208, 109414. https://doi.org/10.1016/j.petrol.2021.109414.
Gu, Z.H., Li, Z.M., Xu, Z.X., Zhang, C., 2022. Microscopic mechanical model analysis and visualization investigation of SiO2 nanoparticle/HPAM polymer foam liquid film displacing heavy oil. Langmuir 38, 9166-9185. https://doi.org/10.1021/acs.langmuir.2c00817.
Hu, J.J., Zhang, G.C., Jiang, P., Ge, J.J., Pei, H.H., Wang, X., 2022. Study on the chemical structure characterization and emulsification-stripping of heavy oil. J. Pet. Sci. Eng. 215, 110592. https://doi.org/10.1016/j.petrol.2022.110592.
Kharrat, A., Brandstätter, B., Borji, M., Ritter, R., Arnold, P., Fritz-Popovski, G., Paris, O., Ott, H., 2022. Development of foam-like emulsion phases in porous media flow. J. Colloid Interface Sci. 608, 1064-1073. https://doi.org/10.1016/j.jcis.2021.10.022.
Li, X.X., Yue, X.A., Zou, J.R., Yan, R.J., 2022. Effect of in-situ emulsification of surfactant on the enhanced oil recovery in low-permeability reservoirs. Colloid. Surface. 634, 127991. https://doi.org/10.1016/j.colsurfa.2021.127991.
Li, Z., Fuentes, J., Chakraborty, A., Zamora, E., Prasad, V., Vázquez, F., Xu, Z.H., Liu, Q.X. César, Flores, McCaffrey, W.C., 2023. Dehydration of water-in-crude oil emulsions using polymeric demulsifiers: a model for water removal based on the viscoelastic properties of the oil–water interfacial film. Fuel 332, 126185. https://doi.org/10.1016/j.fuel.2022.126185.
Liang, T.B., Gu, F.Y., Yao, E.D., Zhang, L.F., Yang, K., Liu, G.H., Zhou, F.J., 2017. Formation damage due to drilling and fracturing fluids and its Solution for tight naturally fractured sandstone reservoirs. Geofluids, 9350967. https://doi.org/10.1155/2017/9350967.
Liu, J.B., Zhong, L.G., Hao, T.C., Ren, L., Liu, Y.G., 2022a. A collaborative emulsification system capable of forming stable small droplets of oil-in-water emulsions for enhancing heavy oil recovery. J. Mol. Liq. 355, 118970. https://doi.org/10.1016/j.molliq.2022.118970.
Liu, J.B., Liu, S., He, Y.X., Zhong, L.G., Hao, T.C., Liu, Y.G., Wang, P., Gao, P.C., Guo, Q.H., 2022b. Experimental study of produced fluid emulsification during water/steam flooding for heavy oil recovery. Energy Fuels. 37, 4308-4319. https://doi.org/10.1021/acs.energyfuels.2c03211.
Liu, J.B., Liu, S., Zhang, W., Zhong, L.G., Hao, Y., Zhang, Y.J., Cai, W.B., Du, H.Y., 2023a. Influence of emulsification characteristics on the pressure dynamics during chemical flooding for oil recovery. Energy Fuels 37, 4308-4319. https://doi.org/10.1021/acs.energyfuels.2c04010.
Liu, J.B., Liu, S., Zhong, L.G., Li, Z.L., Zhang, Y.L., Du, H.Y., 2023b. Porous media flooding mechanism of nanoparticle-enhanced emulsification system. Phys. Fluids 35, 033304. https://doi.org/10.1063/5.0141815.
Liu, J.B., Liu, S., Zhong, L.G., Wang, P., Cao, P.C., Guo, Q.H., 2023c. Ultra-low interfacial tension anionic/cationic surfactants system with excellent emulsification ability for enhanced oil recovery. J. Mol. Liq. 382, 121898. https://doi.org/10.1016/j.molliq.2023.121989.
Liu, J.R., Shenga, J.J., Tu, J.W., 2020. Effect of spontaneous emulsification on oil recovery in tight oil-wet reservoirs. Fuel 279, 118456. https://doi.org/10.1016/j.fuel.2020.118456.
Liu, S., Zhang, Y.L., Du, H.Y., Liu, J.B., Zhou, Z.X., Wang, Z.Z., Hang, K., Pan, B.S., 2023d. Experimental study on fluid flow behaviors of waterflooding fractured-vuggy oil reservoir using two-dimensional visual model. Phys. Fluids 35, 062106. https://doi.org/10.1063/5.0152685.
Liu, T.J., Xu, D.R., Lian, W., Kang, W.L., Sarsenbekuly, B., 2023e. Optimization of injection parameters of a microemulsion-type oil displacement agent for heavy oil recovery. Phys. Fluids 35, 113102. https://doi.org/10.1063/5.0174514.
Ma, J., Yao, M.Q., Yang, Y.L., Zhang, X.Y., 2022. Comprehensive review on stability and demulsification of unconventional heavy oil–water emulsions. J. Mol. Liq. 350, 118510. https://doi.org/10.1016/j.molliq.2022.118510.
Mariyate, J., Bera, A., 2022. A critical review on selection of microemulsions or nanoemulsions for enhanced oil recovery. J. Mol. Liq. 353, 118791. https://doi.org/10.1016/j.molliq.2022.118791.
Mars, M.K., Guzel, T.B., Aleksey, G.T., Alfir, T.A., 2011. Non-equilibrium and nonlinear effects in water-in-oil emulsion flows in porous media. Energy Fuels 25, 1173-1181. https://doi.org/10.1021/ef101053k.
Meng, M., Ge, H., Shen, Y., Ji, W., Li, Z., 2023a. Insight into water occurrence and pore size distribution by nuclear magnetic resonance in marine shale reservoirs, southern China. Energy Fuels 37 (1), 319-327. https://doi.org/10.1021/acs.energyfuels.2c03395.
Meng, M., Zhang, Y., Yuan, B., Li, Z., Zhang, Y., 2023b. Imbibition behavior of oil-saturated rock: implications for enhanced oil recovery in unconventional reservoirs. Energy Fuels 37 (18), 13759-13768. https://doi.org/10.1021/acs.energyfuels.3c02501.
Mohamed, A., Saleh, Arhuoma, 2009. Emulsion Flow in Porous Media and its Application in Alkaline Flooding for Heavy Oil Reservoirs. Ph.D. Dissertation. University of Regina.
Mohammadzadeh Shirazi, M., Ayatollahi, S., Ghotbi, C., 2019. Damage evaluation of acid-oil emulsion and asphaltic sludge formation caused by acidizing of asphaltenic oil reservoir. J. Pet. Sci. Eng. 174, 880-890. https://doi.org/10.1016/j.petrol.2018.11.051.
Onaizi, S.A., 2022. Effect of oil/water ratio on rheological behavior, droplet size, zeta potential, long-term stability, and acid-induced demulsification of crude oil/water nanoemulsions. J. Pet. Sci. Eng. 209, 109857. https://doi.org/10.1016/j.petrol.2021.109857.
Papadimitriou, M.K., Stephanou, P.S., 2022. Modeling the rheological behavior of crude oil–water emulsion. Phys. Fluids 34. https://doi.org/10.1063/5.0123274, 113-107
Patil, A., Arnesen, K., Holte, A., Farooq, U., Brunsvik, A., Størseth, T., Johansen, S.T., 2021. Crude oil characterization with a new dynamic emulsion stability technique. Fuel 290, 120070. https://doi.org/10.1016/j.fuel.2020.120070.
Plasencia, J., Petterson, B., Nydal, O.J., 2013. Pipe flow of water-in-crude oil emulsions: effective viscosity, inversion point and droplet size distribution. J. Pet. Sci. Eng. 101, 35-43. https://doi.org/10.1016/j.petrol.2012.11.009.
Pu, W.F., He, M.M., Yang, X.R., Liu, R., Shen, C., 2022. Experimental study on the key influencing factors of phase inversion and stability of heavy oil emulsion: asphaltene, resin and petroleum acid. Fuel 311, 122631. https://doi.org/10.1016/j.fuel.2021.122631.
Regina, S., 2006. Interfacial Phenomena in Enhanced Heavy Oil Recovery by Alkaline Flood. Ph.D. Dissertation. University of Regina.
Shahsavar, N., Riazi, M., Malayeri, M.R., 2020. Removal of asphaltene deposition in porous media using emulsified solvents—a visual study. J. Pet. Sci. Eng. 191, 107207. https://doi.org/10.1016/j.petrol.2020.107207.
Sousa, A.M., Pereira, M.J., Matos, H.A., 2022. Oil-in-water and water-in-oil emulsions formation and demulsification. J. Pet. Sci. Eng. 210, 110041. https://doi.org/10.1016/j.petrol.2021.110041.
Sun, M., Mogensen, K., Bennetzen, M., Firoozabadi, A., 2016. Demulsifier in injected water for improved recovery of crudes that form water/oil emulsions. SPE J. 19 (4), 664-672. https://doi.org/10.2118/180914-PA.
Sun, Z.Q., Pu, W.F., Zhao, R.B., Pang, S.S., 2022. Study on the mechanism of W/O emulsion flooding to enhance oil recovery for heavy oil reservoir. J. Pet. Sci. Eng. 209, 109899. https://doi.org/10.1016/j.petrol.2021.109899.
Tian, K.P., Pu, W.F., Wang, Q.L., Li, S.Y., Liu, S., Xie, M.K., Wang, Y.B., 2023. Effect of amphiphilic CaCO3 nanoparticles on the plant surfactant saponin solution on the oil−water interface: a feasibility research of rnhanced oil recovery. Energy Fuels 37 (17), 12854-12864. https://doi.org/10.1021/acs.energyfuels.3c02164.
Trallero, J.L., 1995. Oilewater Flow Patterns in Horizontal Pipes. Ph.D Dissertation. The University of Tulsa.
Vladisavljević, G.T., 2015. Structured microparticles with tailored properties produced by membrane emulsification. Adv. Colloid Interfac. 225, 53-87. https://doi.org/10.1016/j.cis.2015.07.013.
Wang, G.Z., Xia, Q.L., 2009. Natural gas distribution characteristics, main controlling factors of accumulation and exploration direction in Bohai Sea. China Offshore Oil Gas 21 (1), 15-18 (in Chinese).
Wang, H.Y., Wei, B., Hou, J., Sun, Z.Z., Du, Q.J., Zhou, K., 2023. Investigation of microflow mechanisms and emulsion size distribution in porous media. Phys. Fluids 35, 091302. https://doi.org/10.1063/5.0171494.
Xue, Y.G., 2018. Understanding and innovation promote new breakthroughs in oil and gas exploration in Bohai Sea area: review of major exploration progress in Bohai Sea area in recent years. China Offshore Oil Gas 30 (2), 1-8 (in Chinese).
Yu, L., Dong, M.Z., Ding, B.X., Yuan, Y.G., 2017. Emulsification of heavy crude oil in brine and its plugging performance in porous media. Chem. Eng. Sci. 178, 335-347. https://doi.org/10.1016/j.ces.2017.12.043.
Zeidani, K., Polikar, M., Huang, H., Boyd, J.W., 2008. Application of emulsion blocking mechanism for sealing the near wellbore region. J. Can. Pet. Technol. 47 (5). https://doi.org/10.2118/08-05-40.
Zhang, F., Jiang, Z.X., Zhang, Y.H., Hu, B., Yang, Z.Q., Yang, Y.H., Tang, X.L., Xiao, H.M., Zhu, L., Han, Y.H., 2023. A new method for converting T2 spectrum into pore radius. J. Earth Sci. 34 (4), 966-974. https://doi.org/10.1007/s12583-021-1576-y.
Zhang, Y.J., Zou, Y., Zhang, Y., Wang, L.Y., Liu, D.Q., Sun, J., Ge, H.K., Zhou, D.S., 2022. Experimental study on characteristics and mechanisms of matrix pressure transmission near the fracture surface during post-fracturing shut-in in tight oil reservoirs. J. Pet. Sci. Eng. 219, 111133. https://doi.org/10.1016/j.petrol.2022.111133.
Zhao, M.W., Yan, X.W., Cheng, Y.L., Yan, R.Q., Dai, C.L., 2022. Study on the imbibition performance and mechanism of a fracturing fluid and its gel breaking liquid. Energy Fuels 36, 13028-13036. https://doi.org/10.1021/acs.energyfuels.2c02869.
Zhong, L.G., Liu, J.B., Yuan, X.N., Wang, C., 2022. Subsurface sludge sequestration in cyclic steam stimulated heavy-oil reservoir in Liaohe Oil Field. SPE J. 25 (3), 1113-1127. https://doi.org/10.2118/195415-PA.